Adsorption of tartrazine on an iron modified zeolitic tuff
1 National Institute of Nuclear Research, Department of Chemistry, Street Mexico-Toluca s/n, La Marquesa, Ocoyoacac, Edo. De Mexico C. P. 52750, Mexico
2 Technological Institute of Toluca, Division of Postgraduate Studies, Av. Tecnologico s/n, Ex Rancho La Virgen, C.P. 52140, Metepec, Estado de M xico, M xico
3 Technological Institute of Toluca, Division of Postgraduate Studies, Av. Tecnologico s/n, Ex Rancho La Virgen, C.P. 52140, Metepec, Estado de M xico, M xico
2 Technological Institute of Toluca, Division of Postgraduate Studies, Av. Tecnologico s/n, Ex Rancho La Virgen, C.P. 52140, Metepec, Estado de M xico, M xico
3 Technological Institute of Toluca, Division of Postgraduate Studies, Av. Tecnologico s/n, Ex Rancho La Virgen, C.P. 52140, Metepec, Estado de M xico, M xico
Abstract
The adsorption of tartrazine from aqueous solution was evaluated using an iron (III) modified zeolitic tuff. The adsorbent was characterized by scanning electron microscopy and X-ray power diffraction; the modification process does not affect the crystalline structure of the zeolitic tuff. Sorption kinetic, isotherms, dose and pH effects were determined and the adsorption behavior was analyzed. The sorption equilibrium was reached in 72 hours, the adsorption capacity determined by the Langmuir model was 1.05 mg/g. Sorption capacity of Fe-zeolitic tuff for tartrazine was not influenced by pH. Kinetic pseudo-second order and Freundlich models were successfully applied to the experimental results, indicating that the adsorption process was chemisorption on a heterogeneous material.
Keywords
adsorption; equilibrium; Fe-zeolitic tuff; tartrazine