Ammonium adsorption on oxidized exfoliated graphite nanoplatelets

Daniela Bogdan1, Al-Ogaidi Ahmed Jassim Muklive1,2, Ion Ion1, Alina Catrinel Ion1

1 University Politehnica of Bucharest, Department of Analytical Chemistry and Environmental Engineering, Polizu street no. 1-7, 011061, Bucharest, Romania
2 University of Technology, Department of Applied Sciences, Al-Senaa street, Baghdad, Irak

Abstract


Ammonium is an environmental contaminant encountered in water and soils, its admissible concentrations in soils and waters being established by legislation. Removal of ammonium ions from aqueous solutions from different matrix can be done with several sorbents, among which nano-adsorbents, such as oxidized exfoliated graphite nanoplatelets (ox-xGnP) offer practical solutions, based on their high specific surface area, associated sorption sites and efficiency of application. Several parameters such as pH, temperature and contact time was studied and kinetic and isotherm models were validated to understand the mechanism of adsorption of ammonium by ox-xGnP. The obtained results demonstrated that exfoliated graphite nanoplatelets could be employed as an effective adsorbent for ammonium.

Keywords


adsorption; ammonium; oxidized exfoliated graphite nanoplatelets

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